All posts by dannik

Shampoo Production: From History to the Modern World

Shampoo is one of the most important and widespread hair-care products in the national and international markets.  The international financial crises of 2008 did damage to many branches of industry worldwide.  Some of them are still  trying to recover to their pre-crisis-levels.  Despite the 2008 crisis, the market for household wares, including shampoo did not suffer and actually has seen steady growth.

Manufacturers have changed their needs and preferences due to the 2008 crisis, but not the average consumer.  Consumer goods such as soap, shampoo and detergent always enjoy a wide popularity regardless of the macroeconomic situation.

The rate of inflation usually affects the salary of ordinary people, but very rarely does it effect their taste.  Additionally, positive tendencies in the home care market are observed every year.  For example, about 40,000 new beauty care products appear on the market each year.

Shampoos became a part of everyday life in the 1960s.  This was due in part to the production of the efficient surface-active substance known in the industry as ethoxylated sodium lauryl sulfate.

Today, the size of the beauty care market is growing by 10% each year.  Given that 90% of the world’s population uses shampoo on a daily basis, demand will continue to increase as the global population increases.

According to the analysts of the Discovery Research Group, the volume of the hair care products market as of 2010 was about 3.3 billion dollars.  The home care market is characterized by import dependence.  More than 80% of the raw materials used for the production of cosmetics and care products is not produced domestically, but is imported from countries all around the world.

Soap and shampoo companies use modern equipment to obtain high-quality and efficient soap mixtures that serve as cleaning agents with no harm to human health.  Additionally, cosmetic product establishments follow the development of the technology market and its latest offers to remain efficient and cost effective.

At production facilities, shampoo is made from chemical components that are thoroughly blended.  Modern shampoo consists of water, surface-active agents, additives, favors and non-organic salts to maintain its viscosity.  The composition of the shampoo surface layer may be compared with biological fuel and chemical mixtures that are becoming more and more popular in the oil products market.  Natural oils and vitamins serve as additives.  That is why the fuel blending systems, used at industrial and energy production facilities can be also used to produce personal care products such as shampoos, soaps and detergents.

These versatile industrial blending units are designed to blend water and various liquid components with active natural and alcohol additives to improve the final product.

The blending equipment, that  was once considered to be an object of luxury even for industrial manufacturers, has now become an integral part of any technological blending process that is connected with liquid blending.

Due to these modern blending units, manufacturers can produce shampoo that is characterized by low power consumption, possibility to perform different technological processes on one unit and trouble-free operation.

A High-Level Task: Blending of Industrial Solutions

The expression: “blending of solutions,” takes us back many years to our high school chemistry class.  The calculation of the mass fraction of the matter, dissolved in a solution; the mass of dissolved matter in a solution; the mass of solution, these are things that seemed to be unnecessary when we were young students.

In today’s modern world, people can buy most anything.  The only question is the price.  Whether you own a small or big enterprise, you should play by the rules of the market and profit from it as much as possible.  No self-respecting businessman will intentionally waste his company’s money.

In speaking about Industrial Solutions, it is safe to assume that they are one of the main raw materials of many industrial production processes.  There exist many ways to blend different solutions for various branches of industry.

GlobeCore has developed one of the most effective and safe methods of blending industrial solutions.  The modern equipment for production and blending of solutions makes the daily work of any company efficient and safe.  Sometimes the standard equipment for the production and blending of construction or industrial solutions does not meet the individual needs of a customer.

That is why GlobeCore always considers the wishes of its customers and offers individual solutions to meet the needs of a particular client.

GlobeCore’s  engineers design equipment that meets the individual needs of the customer and complies with international quality standards and national labor safety regulations.

GlobeCore’s USB blending units are designed to blend liquid components of various industrial solutions.  High-quality assembly and individual design provide for reliable and trouble-free operation of equipment for many years of service.

Maintenance of the USB blending systems does not require specially trained staff since the operating program is set prior to commissioning and does not need reconfiguration one in operation.

The GlobeCore USB line of blending units has shown itself to good advantage, being reliable and long lasting equipment.

Commercial Grade Diesel Fuel Production

The units in GlobeCore’s USB line provide for production of high-quality commercial grade diesel fuel from cheap or inexpensive components.  The high-quality commercial grade diesel fuels such as Euro-2,3,4, and 5 can be made from inexpensive components due to the hydrodynamic cavitation technology found in GlobeCore’s advanced equipment.

The following components may be used to produce summer diesel fuel:

  • light stove fuel;
  • old, segregated and contaminated diesel fuel
  • dark stove fuel;
  • used oil; and
  • biodiesel fuel.

Additionally, different additives that increase the cetane number of the final product may also be used when producing diesel fuel with GlobeCore USB units.

The following is the technological process of commercial-grade diesel fuel production. First, original components are purified and then, together with metered additives, are supplied to the hydrodynamic blender to be processed.  As a result, there is commercial-grade diesel fuel that meets customer’s needs.

Diesel fuel, obtainted by using GlobeCore USB equipment, is homogeneous and does not separate if it is stored even for a long periods of time. Cavitation technologies allow for water to be included into the fuel production process.

Diesel fuel, that contains approximately15% of water by volume, is able to eliminate hazardous waste emissions and is very important and useful when working in poorly ventilated production facilities.

Production of Multicomponent Mixed Fuels

GlobeCore’s line USB units produce high-quality mixed fuels as well as ensuring their homogenization.  All the fuel components are supplied to a common collector through a blending process that is realized in a hydrodynamic mixer.

The following is the list of the components used in fuel blending:

  • low-octane gasoline;
  • distilled gasoline;
  • stable gas gasoline;
  • biological components of motor oils; and
  • additives that increase gasoline’s octane rating.

The main benefits of GlobeCore USB units are as follows:

(1)    precise components for metering and control;

(2)    reduced blending cycle times; and

(3)    no mixing tanks for final product homogenization;

If the resuling mixture is properly homogenized, it will not separate into its component parts even if it is stored for a long period of time.

Petrol: Additives and Coefficient-Factor

Gasoline is one of the most expensive sources of energy.  The process of its production is very complicated and includes primary and secondary stages of oil processing at refineries as well as the introduction of various additives.

In practical terms, oil refineries use such additives as MTBE (Methyl tert-butyl ether) and ETBE (Ethyl tert-butyl ether) to obtain gasoline with defined characteristics.  In general, additives constitute not more than 8 to 10% of the total amount of substances in gasoline.  Of course, the price of the finished product is heavily influenced by the price of the additives.

It is therefore, oil refineries, as well as traders, that find it very important to price the additives in a proper way.  Nowadays, the coefficient-factor helps to indicate the price ratio index ‘additive-petrol’ and reflects a correlation among the petrol components that is of great practical value.  Table 1 shows the coefficient-factors as of August-November 2010.

Table 1

The coefficient-factors as of August-November 2010

No.

Date

10 ppm

MTBE

Coefficient-factor

ETBE

Coefficient-factor

1

27/08/10

690.0

765.0

1.1

979.0

1.42

2

15/09/2010

728.0

857.0

1.18

1070.0

1.47

3

12/10/2010

790.0

890.0

1.13

1090.0

1.38

4

09/11/2010

784.0

875.0

1.12

991.0

1.26

Mainly, the MTBE price has been determined by the 10 ppm petrol price as of August-November 2010.  In this case, the coefficient-factor was stable though it was low (1.1-1.18).  It is therefore, the import of MTBE from the Persian Gulf countries that has been reduced.  Such additives as ETBE was characterised by sufficiently high European prices (1070-1090 dollars per ton).  It was due to the fact that the price for ethanol in Europe was very high.  Additionally, there was an increase in ETBE consumption in countries of the European Union as compared with MTBE in accordance with the Directive 2009/28/EC.  Table 2 shows the European prices for fuels as of August-November 2010.

Table 2

Fuel prices NWE ARA

No.

Name

27/08/10

15/09/10

12/10/10

09/11/10

1

Brent

75.02

79.16

83.70

88.46

2

Gasoline 10 ppm

690.0

728.0

790.0

784.0

3

MTBE

765.0

857.0

890.0

875.0

4

Methаnоl T1

290.0

359.0

387.0

387.0

5

ETBE

979.0

1070.0

1090.0

991.0

6

Methаnоl T1

756.0

805.0

827.0

846.0

7

Ethanol T2

979.0

1030.0

1067.0

1085.0

The cost of raw material, used to produce ethers is considered to be the most important factor that determines the price of additives.  Approximately 50 % of the ETBE is accounted for fuel ethanol.  MTBE contains 33% methanol.

Table 3 shows prices for petrol and ethanol all over the world as of November 23, 2010.

Table 3

The prices for ethanol and gasoline in the world (November 23, 2010), $

Ethanol (T2) (Rotterdam)

Ethanol (Brazil)

Ethanol (the USA)

Ethanol (Ukraine)

Gasoline Regular (the USA)

Gasoline A-95 (Russia)

Gasoline Super 95 10 ppm (Germany)

0.82

0.69

0.55

0.81

0.75

0.64

1.96

As the table shows, the cheapest gasoline was in Russia and the most expensive – in Germany.  In the USA, ethanol was the cheapest when in Ukraine and Rotterdam it was considered to be the most expensive.

Fuel Oil Emulsions

Nowadays much importance is placed on the problems of energy saving and environmental safety. In particular, these issues are of great significance while servicing fuel equipment.

The water-fuel emulsions are proved to contribute to conservation of fuel and energy resources and improve environmental conditions.  The water-fuel emulsion may consist of different components such as:

(1) water – fuel oil;

(2) water – diesel oil;

(3) water – gasoline; and

(4) water- fuel oil – coal dust.

Water that has entered into fuel oil during transportation, storing or warming up increases its viscosity and it may have negative consequences.  But properly prepared water-fuel emulsions makes it possible to achieve good results.

Often, the content of  water in fuel oil exceeds the admissible limit value (12-16% instead of 1.5 %). It may be difficult to separate water from fuel by sedimentation as density of water and fuel oil are almost the same.  Water does not settle to the bottom of the container and distributes unevenly in the diesel fuel.  As a result, the flame is disturbed, the injectors go out slowly and sometimes it may be troublesome to fire the injectors.

Restarting of the boiler units can cause strong puffs and damages because of accumulated combustible gases.  The regulatory documents state that the water content of the fuel oil that is to be burnt must be 0.3 -1 %.

According to the traditional technologies, there are only two procedures of fuel oil preparation: dehydration and heating.  Water expulsion is an energy-consuming process that leads to the loss of fuel volatile components.

As previously mentioned, sedimentation is time-consuming and does not provide a desirable effect. It is not reasonable to apply chemical or biological methods since they require additional areas, operational and financial expenditures.

The fuel oil emulsion combustion provides for substantial economic effect, improves boiler’s efficiency (3-5 %) and reduces the amount of harmful discharges into the air.

The significant cost savings are possible when adding 10-15% of water into the fuel oil.  More than 20 % of water in the emulsion will lower the quality of the combustion process.  But it is desirable to increase the water content with a view to the waste water disposal. If to increase the water content in fuel oil emulsion up to 50 %, there may be observed some positive environmental impacts since waste water is the main component of the fuel oil emulsion.

The use of homogenized fuel oil emulsion allows for fuel saving, reduction of such discharges as NO x and CO x and improves the quality of the fuel combustion.

How are these effects achieved?

The atomizer disperses fuel oil that is supplied to the burner.  The size of the droplets should be 0.1 – 1 mm.  If there is water in the droplets, it will turn into vapor when heated.  The dispersion of the fuel, being supplied to the burner is increased due to the breakdown of the fuel oil droplets.

Additionally, the fuel and air contact area is extended that will lead to the improvement of the fuel-air mixture quality.  The homogenized fuel oil emulsion is less viscous than fuel oil, which makes the fuel transfer process much easier.

No less important factor that weighs in favour of fuel oil emulsions is that they benefit the durability of the fuel firing equipment.

How to achieve all these effects?

The answer is simple – just to make finely-dispersed and non-segregating fuel oil emulsion. GlobeCore has developed and is still producing  the USB units that contribute to the fuel oil emulsion production.  They are designed to blend liquid petroleum products such as fuel oil, diesel oil or stove fuel with additives and water.  The USB units are equipped with high-accurate electronic control system that ensures the precise metering of components.

The ready-made emulsions can be applied in any heating equipment and stored during a long period of time without settling.

How To Save Heavy Fuel Oil?

The biggest problem of nowadays is that people have never thought that fuel and power resources are at risk of becoming depleted.  Future generations may pay a high price for such wastefulness of their ancestors.

Heavy fuel oil enjoys a wide application in housing maintenance and utility.

It is difficult to find a boiler house that does not use this dark brown substance to produce heat.

One of the major benefits of heavy fuel oil is its high energy value: 1 kilogram of such substance is able to produce 9150 kilocalories of heat while burning.  If to compare diesel fuel and heavy fuel oil, used for house heating, the latter is proved to be much cheaper.  Viscosity is considered to be one of the essential performance characteristics of heavy fuel oil and depends on the heating temperature.  The fuel oil consumption rate is measured at 80-100ºC/176- 212ºF.

Heavy fuel oil should be pre-warmed because its high viscosity doesn’t allow it to be applied immediately.  It is warmed up by hot steam, but there may be negative consequences as condensed steam may get into the heavy oil fuel and hamper the burning process. As a result, the amount of heat being generated is significantly reduced.

Therefore, much fuel is needed to compensate the losses which will result in significant financial expenditures.  As this method has no chance of success, there should be found another way out.  A method of sedimentation is often used to separate water from oil products.  Though this method is considered very effective, it doesn’t work in cases with heavy fuel oil.  The water is difficult to separate from the oil product since its density is the same as that of heavy fuel oil.  But even in summer, some water may get into the fuel when stored for a long time.

Fuel oil emulsion however, has become an optimal solution to many problems.

The main problem is that it is very difficult to make the obtained substance finely-divided and stable.  Therefore, GlоbeCоre has developed the USB unit that is designed to make finely-divided and high-stable emulsions, based on liquid oil products (heavy fuel oil, diesel oil) and water (pure or waste waters, sream).

Heavy fuel oil efficiency is achieved due to its emulsification in the USB unit.  As a result, the efficiency of the boiler unit is increased as well and provided by such factors as:

(1) water is evenly distributed through the whole substance;

(2) fragmentation and incineration of substance inside the furnace are provided by low fanning blast, eliminating the risk of underburnings;

(3) the emulsion droplets are grinded down in the furnace; and

(4) stack gasses heat recovery;

The fuel oil emulsion gives the possibility of reducing by two times the smoke emissions and three to four times the carbon black emissions.  The benefits of fuel oil emulsion application are given below.

The advantages of fuel oil emulsion

Table 1

Factors that may contribute to fuel oil saving Percentage of fuel oil saving
The emulsification of water, contained in the heavy fuel oil, supplied for burning up to 2%
Reduction of the excess air ration in furnace by 0.1 0.7%
Reduction in temperature of stack gases by 10°С / 50°F 0.6%
Reduction in temperature of feed water, heated in the unit-type economizer by 10 °C / 50°F 1.6%
Reduction in temperature of feed water that enters the unit type economizer by 10 °C / 50°F 0.24%
Carbon back emissions reduction up to 0.2%
clean heat-exchange surfaces of boiler up to 2%
Reduction in temperature of fuel oil heating by 30 °C / 86 °F up to 1%
Substitution of steam-atomizing injectors by mechanical atomizing injectors up to 1%
Maintaining the efficiency of the heat unit while operating at 75% nominal capacity 0.7%
Fuel loss due to evaporation of water, contained in emulsion 0.8%
Possible total fuel savings (including fuel loss due to evaporation of water, contained in emulsion). up to 10%

Heavy-Fuel Oil Savings

Heavy fuel oil is a dark brown liquid that is obtained from petroleum distillation.  Though the composition of heavy fuel oil may vary, there are such basic components as:

(1) long residuum;

(2) tar;

(3) vacuum gas oils;

(4) kerosine-gas oil fractions;

(5) catalytic gas oil;

(6) coker gas oil;

(7) visbreaker tar; and

(8) heavy resins of pyrolysis.

Nowadays, heavy fuel oil enjoys wide application while producing motor fuel or bunker oil and when heating homes due to such performance characteristics as:

(1) high calorific value; and

(2) low ash content;

Additionally, heavy fuel oil provides a luminous flame that ensures good heat transfer in the combustion chamber.

As any other product, furnace fuel oil has some drawbacks such as:

(1) Increased safety requirements;

(2) high sulphur content (about 3.5 %); and

(3) high freezing point (25-30ºС/77-86ºF).

Despite all the drawbacks, heavy fuel oil is still in demand.  Far-sighted use of resources is provided by significant reduction in the fuel and energy resources.

Every year people are trying to find new ways how to save on residential heating costs.  Additionally, the major attempts should be directed to the reduction of harmful discharges into the air resulting from the combustion process.

In our opinion, the solution to many problems may be found in the processing of heavy fuel oil before it is burned in the combustion process.  This method consists in the preparation of fuel oil emulsion that has such advantages as:

(1) fuel combustion intensification ;

(2) waste water disposal; and

(3) reduction of CO2 or NOX emissions;

You may wonder: “Why is this method considered to be cost saving?”.  It’s quite simple: The emulsion consists of the components that are cheaper than heavy fuel oil itself.

To prepare fuel oil emulsion, there may be needed such additives as:

(1) clean water;

(2) water that has been used to blow down into boilers;

(3) water vapor; and

(4) Waste water, contaminated by oil products.

One should remember that a desirable effect from the combustion of fuel oil emulsion may be obtained only if it is prepared in a proper way.  First, a special homogeneous mixture type “water-oil” is prepared.  The diameter of the water droplets constituting a dispersed phase is a few microns.  The properly prepared fuel oil emulsion provides good ignition and stable combustion of fuel.

And now little remains to be done – to choose equipment which provides for the production of high-quality fuel oil emulsion.

Globe Core has developed and is still producing  the USB units that are designed for production of fine emulsion, consisting of liquid oil products (heavy fuel oil, diesel fuel, stove fuel, or oil-sludge) and different additives.

The final product can be transported and stored for a long period of time. Additionally, it benefits the reduction of harmful discharges into the air and allows for cost reduction.

Fuel Requirements

All fuel requirements can be roughly divided into four groups such as (1) those related to engine operation, (2) transportation and handling, (3) mass production, and (4) the environment.

Evaporation is considered to be the most important performance characteristic of fuel. It is characterized by (1) fractional composition of fuel, (2) pressure of the saturated vapor, and (3) antiknock rating.  The environmental requirements impose restrictions on the non-saturated aromatic hydrocarbons, sulphur compounds, and antiknock agents.

The Fuel Analysis

The typical fuel found at gas stations is a mixture is the result of various technological processes.

The GlobeCore USB type blending units, for production of multicomponent fuels, has gained a wide popularity recently.  Operating properties of fuel depend on the content and the interaction of the hydrocarbons.

The quality of the product, or its components, is assessed at the oil refineries by laboratory methods that provide information about physical and chemical characteristics of the product. Then, the results are compared with the characteristics specified in special regulations.

Special attention is paid to such fuel characteristics as the octane number (determined on the basis of motor and research methods), density, fraction composition, the content of lead and oxygen, aromatic compounds, and other performance characteristics.

The quality of the blending components and the characteristics of the final product should be under strict control in the course of the compounding process.  Product quality analysis is realized by the online analyzer (analyzer in the infrared region).  It allows the operators to obtain results quickly as well as to take a wide range of the additional readings (apart from the basic ones) from one sample.  The monitoring of the blending processes is realized due to the automation process.

The analysis of the blending process quality allow the operators to fulfil such  tasks as:

(1) to improve the output quality;

(2) to reduce the costs for laboratory tests; and

(3) to receive information on the process parameters in the real-time.

The octane number may be received no earlier than in 1 hour due to the standard laboratory-based methods.  But, in fact, this process typicall takes 2 or 3 hours.

It is however, the octane number that may be determined by the rapid test methods that have gained widespread acceptance.  These methods are based on the spectral analysis, including the analysis of the IR (infrared) region.

Fuel is characterized by the IR spectrum, which allows the operators to define such characteristics of fuel as its fractional composition and the octane number.

Performance Characteristics of the High-Quality Windshield Washer Fluid

High-quality windshield washer fluid should have such performance characteristics as a low freezing point, cleaning and antistatic properties.  Every windshield washer fluid will contain two main components such as the solvent and surface-active substances.

The monobasic alcohols and glycols act as the solvents that lower the freezing point of the washer fluid and dissolve oil compounds.  The surface active substances are needed to remove fats from the windshield.

The composition of the windshield washer fluid

The basic components of washer fluid are ethyl, methyl, and isopropyl alcohols.  The choice of the components of the washer fluid is greatly determined by their cost.  For example, methyl alcohol is cheaper than isopropyl alcohol but its performance characteristics are not as good.

Companies that have years of experience will prefer high-quality raw materials despite the fact that they can be confronted with such difficulties as acquisition of additional licenses, quotas, permits, and certificates.  It is worth noting that in some countries. the production and the realization of windshield washer fluid, based on some alcohols, is prohibited because of the risk to human health.

The surface-active substances remove oil and soot residues, dirt, and fats.  They are so active that between 1-2% of these substances may be enough to make the windshield crystal clean.  There also may be some other additives as components of the windshield washer fluid.  For example, there is a component that covers glass with a thin film.  The latter can change the refraction angle of sunlight that keeps the windshield clear for two weeks.  Additionally, windshield washer fluid can include aromatics that are used to render a fluid a marketable state and subdue the smell of alcohol.  And the last, but not least important, component of the washer fluid is water.

All high-quality windshield washer fluids are made on the basis of  water drawn from artesian wells, or just distilled water. Tap water cannot be used in  most windshield washer fluid production because of additives placed in the water by municipal water systems.

Safety Measures

It is not recommended to use the windshield washer fluid in a traffic jam.  If the vehicle is not moving, the harmful vapors can easily penetrate into the passenger compartment.  If there are some symptoms of poisoning, the driver should shut down the engine, leave the car and breathe fresh until he stars to feel better.  Keep in mind that some alcohols can be accumulated in the human body and cause poisoning over time.

The Performance Characteristics of High-Quality Windshield Washer Fluid

Not every washer fluid factory is able to produce a high-quality product.  If the driver decided to buy the windshield washer fluid, he has to know how to distinguish high-quality washer fluid from low-quality fluid.

Here are the main performance characteristics of high-quality windshield washer fluid:

(1) The surface-active substances. Shake the container with fluid.  The stable foam on the surface of the fluid means that there are active-surface substances.  If the foam does not appear, it is better to select a different brand to purchase;

(2) Transparence.  If the windshield washer fluid is of high quality, there will be no sediments on the bottom of the container;

(3) Packaging.  It is recommended to buy washer fluid only in transparent containers with high-quality labels and caps; and

(4)  The label. The label should include such points as:

(1) the composition of the washer liquid;

(2) freezing temperature;

(3) the manufacturer’ s address; and

(4) the number of the sanitary and epidemiological inspection report.

This report ensures that the product has no risks to human health and does not contain the poisonous substances such as methanol.